In Kagome metal CsVSb, multiple intertwined orders are accompanied by both electronic and structural instabilities. These exotic orders have attracted much recent attention, but their origins remain elusive. The newly discovered CsTiBi is a Ti-based Kagome metal to parallel CsVSb. Here, we report angle-resolved photoemission experiments and first-principles calculations on pristine and Cs-doped CsTiBi samples. Our results reveal that the van Hove singularity (vHS) in CsTiBi can be tuned in a large energy range without structural instability, different from that in CsVSb. As such, CsTiBi provides a complementary platform to disentangle and investigate the electronic instability with a tunable vHS in Kagome metals.

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