We show that NV centers could provide distinct signatures of emergent gauge fields in certain phase transitions in spin liquids. We consider the relaxation rate of a diamond NV center placed a distance above a crystal consisting of two dimensional layers which hosts a quantum spin liquid with spinon Fermi surface. We show that during a spinon pairing transition from a to a spin liquid, the relaxation rate exhibits a rapid fall just below the pairing transition. The drop is much faster than what can be accounted for by the opening of the energy gap. Instead, the rapid fall with a unique dependence of its height and width, is the signature of the Meissner effect of the gauge field. We identify the organic ET compound which has a phase transition at 6K as a candidate for the experimental observation of this phenomenon.

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