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We study the mixing effects in the semileptonic decays the doubly charm baryons of . We focus on the ratio of and find that with , which are in sharp contrast to without the mixing. The ratio is enhanced~(suppressed) by a factor of four for a negative~(positive) . In addition, the polarization asymmetries of are found to be and . As and are highly sensitive to and unaffected by the -exchange contributions, they provide excellent opportunities to determine in the ongoing experiments.

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