This paper presents a comprehensive analysis of the driven cubic-quintic Duffing oscillator advancing both analytical and numerical chaos theory. Using Melnikov analysis on explicit homoclinic orbits we rigorously predict transverse homoclinic intersections and limit cycle bifurcations surrounding the hyperbolic saddle , establishing chaos onset at . A groundbreaking contribution introduces the hybrid quintic Duffing-Riemann zeta system , where via C-transformation decomposition. Bifurcation portraits reveal zeta perturbation delays chaos by () while enhancing Lyapunov exponents by (). Nontrivial zeros emerge as chaos suppressors through entropy-matching . We prove nontrivial zeros manifest as global Lyapunov minimizers , reformulating the Riemann Hypothesis as a verifiable bifurcation prediction. The unperturbed Hamiltonian and stochastic extensions for biomedical applications are analyzed, positioning number-theoretic chaos control as a novel paradigm bridging nonlinear dynamics and analytic number theory.

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