By analyzing (10087±44)×106 J/ψ events collected with the BESIII detector at the BEPCII, the decays J/ψ→Ξ0ΛˉKS0+c.c., J/ψ→Ξ0Σˉ0KS0+c.c., and J/ψ→Ξ0Σˉ−K++c.c. are observed for the first time. Their branching fractions are determined to be B(J/ψ→Ξ0ΛˉKS0+c.c.)=(3.76±0.14±0.23)×10−5, B(J/ψ→Ξ0Σˉ0KS0+c.c.)=(2.24±0.32±0.31)×10−5, and B(J/ψ→Ξ0Σˉ−K++c.c.)=(5.64±0.17±0.28)×10−5, where the first uncertainties are statistical and the second systematic.