Let be a countable discrete group. Given any sequence of -normalized functions (), consider the associated positive definite matrix coefficients of the right regular representation . We construct an orthogonal decomposition of the corresponding {\it Schur multipliers} on the reduced group -algebra or the uniform Roe algebra of . We identify this decomposition explicitly via the limit points of the orbits in the group-invariant compactification of the quotient space constructed by Varadhan and the first author in [14]. We apply this result and use positive-definiteness to provide two (quite different) characterizations of amenability of – one via a variational approach and the other using group-invariant percolation on Cayley graphs constructed by Benjamini, Lyons, Peres and Schramm [1]. These results underline, from a new point of view to the best of our knowledge, the manner in which Schur multipliers capture geometric properties of the underlying group .

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