Room-temperature magnetoelectric multiferroicity has been observed in c-axis oriented GaFeO thin films (space group ), grown on economic and technologically important (100)Si substrates by pulsed laser deposition technique. Structural analysis and comprehensive mapping of Ga:Fe ratio across a length scale range of 10 reveal coexistence of epitaxial and chemical strain. It induces formation of finer magnetic domains and large magnetoelectric coupling - decrease in remanent polarization by 21% under 50 kOe. Magnetic force microscopy reveals presence of both finer (100 nm) and coarser (2 m) magnetic domains. Strong multiferroicity in epitaxial GaFeO thin films, grown on (100)Si substrate, brighten the prospect of their integration with Si-based electronics and could pave the way for development of economic and more efficient electromechanical, electrooptic or magnetoelectric sensor devices.

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