Bound states in the continuum (BICs) in photonic slabs and metasurfaces appear as polarization singularities in momentum space, characterized by an integer winding number. This winding is widely treated as a robust topological label, preserved under smooth deformations of the structure. Here we show that this robustness fails under band inversion. Using a general two-band theory of open periodic photonic structures, we prove that a band inversion at a band-edge BIC reverses the local far-field polarization map and flips the BIC winding, , \emph{without} any defect dynamics in momentum space. We verify the prediction in a tunable subwavelength grating, where polarization tomography directly images the reversal, and confirm it numerically in multiband rectangular and triangular photonic lattices. Band inversion thus emerges as a key mechanism governing polarization-singularity topology in non-Hermitian photonic band structures.

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