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We establish a novel correspondence between 4D supersymmetric gauge theories on and open XYZ spin chains with generalized boundary conditions, extending beyond previous 3D Bethe/gauge duality frameworks. Our primary contribution is the rigorous construction of the first exact duality between 4D BCD-type gauge theories and general-boundary XYZ spin chains governed by elliptic -matrices. This framework provides a universal mechanism for resolving supersymmetric gauge theory/spin-chain duality across dimensional hierarchies: 2D XXX spin chain, 3D XXZ spin chain, 4D XYZ spin chain, mediated through the -deformation parameter .

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