The nonattractor evolution in ultra-slow-roll (USR) inflation results in the amplification of superhorizon curvature perturbations and then induces a strong and detectable stochastic gravitational wave background. In this letter, we search for such a stochastic gravitational wave background in data from the third LIGO-Virgo observing run and place constraints on the USR inflationary models. The -folding number of the USR phase are constrained to be at the 95% confidence level and the power spectrum of curvature perturbations amplified during the USR phase is constrained to be at the scales . Besides, we forecast the ability of future experiments to constrain USR inflation, and find for LISA and Taiji, for Cosmic Explore and Einstein Telescope, for DECIGO and Big Bang Observer and for Square Kilometre Array.

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