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We prove a conjectural vanishing result for Gopakumar–Vafa invariants of quintic 3-folds, referred to as Castelnuovo bound in the literature. Furthermore, we calculate Gopakumar–Vafa invariants at Castelnuovo bound . As physicists showed, these two properties allow us to compute all Gromov–Witten invariants of quintic 3-folds up to genus , provided that the conifold gap condition holds. We also give a bound for the genus of any one-dimensional closed subscheme in a smooth hypersurface of degree , which may be of independent interest.

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