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We report the synthesis, structure and nonlinear optical properties of cadmium sulphide (CdS) nanocrystallines (NCs) synthesized electrochemically both with and without detergent ATLAS G3300. Relevant structural and morphological features are explored by X-ray diffraction and scanning electron microscopy (SEM) techniques. The efficiency of the second harmonic generation (SHG) appears to be strongly dependent on the energy density of the incident fundamental laser radiation and NC sizes.

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