Probing the valence quark region of nucleons with Z bosons at LHCb

In this high-$x$ region, both the flavour content and structure of the nucleon parton distribution functions remains relatively poorly known. New LHCb measurements of Z and charm jet associated production could indicate a valence-like intrinsic-charm component in the proton wave function, and measurements of Z production in pPb collisions provide new constraints on the partonic structure of nucleons bound inside nuclei. Here we will discuss these new LHCb measurements and comparisons with state-of-the-art parton distribution function calculations.