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We present a new correspondence between acyclic orientations and coloring of a signed graph (symmetric graph). Goodall et al. introduced a bivariate chromatic polynomial that counts the number of signed colorings using colors along with symmetric colors . We show that the evaluation of the bivariate chromatic polynomial is equal to the number of acyclic orientations of the signed graph modulo the equivalence relation generated by swapping sources and sinks. We present three proofs of this fact, a proof using toric hyperplane arrangements, a proof using deletion-contraction, and a direct proof.

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