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We analytically study scalarization of higher-dimensional charged Reissner-Nordström (RN) black hole. It is shown that static massive scalar field which is non-minimally coupled to Gauss-Bonnet invariant can be supported by higher-dimensional black hole in super-critical charge regime with charge and mass of the black hole and some unitless spacetime dimension-dependent quantity. Moreover, we show that the static massive scalar shell can be quite thin in the large mass regime with mass of the scalar field.

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