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We study nearest-neighbour correlation functions for the ground state of the supersymmetric XYZ spin chain with odd length and periodic boundary conditions. Under a technical assumption related to the -operator of the corresponding eight-vertex model, we show that they can be expressed exactly in terms of the Painlevé VI tau functions and introduced by Bazhanov and Mangazeev. Furthermore, we give an interpretation of the correlation functions in terms of the Painlevé VI Hamiltonian.

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