We examine the virtual transition of an atom-mirror system with the simultaneous emission of two scalar photons, where the atom and the mirror admit a relative acceleration between them. For the single photon emission, literature (Phys. Rev. Lett. 121 (2018) 071301) dictates that the transition probabilities of two individual systems, such as an atom accelerating with respect to the mirror and its reverse, turn out to be equivalent under the exchange of the frequencies of atom and the field. Addressing the observational merit of such excitation process, a detectable probability () is also reported in the above literature. In the present manuscript our finding dictates that the simultaneous emission of dual photon instead of one, destroys the equivalence between the transition probabilities as reported in the above literature.

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