The rare-earth nitrides form a series of structurally simple ferromagnetic semiconductors, a rare class of both fundamental interest and application potential. Within the series there is a wide range of magnetic properties relating to the spin/orbit contributions to the ferromagnetic ground states. We report an x-ray magnetic circular dichroism investigation of the spin/orbit magnetic dipole alignments of Sm and Gd ions in epitaxial GdSmN films. The Sm spin-alignment expectation value is seen to be strengthened by the Gd/Sm exchange interaction, providing guidance concerning the composition for an angular momentum compensation point (where the volume-averaged total angular momentum of a film is zero).

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