We present lattice QCD calculations of valence parton distribution function (PDF) of pion employing next-to-next-leading-order (NNLO) perturbative QCD matching. Our calculations are based on three gauge ensembles of 2+1 flavor highly improved staggered quarks and Wilson–Clover valance quarks, corresponding to pion mass ~MeV at a lattice spacing ~fm and ~MeV at ~fm. This enables us to present, for the first time, continuum-extrapolated lattice QCD results for NNLO valence PDF of the pion at the physical point. Applying leading-twist expansion for renormalization group invariant (RGI) ratios of bi-local pion matrix elements with NNLO Wilson coefficients we extract , and Mellin moments of the PDF. We reconstruct the Bjorken- dependence of the NNLO PDF from real-space RGI ratios using a deep neural network (DNN) as well as from momentum-space matrix elements renormalized using a hybrid-scheme. All our results are in broad agreement with the results of global fits to the experimental data carried out by the xFitter and JAM collaborations.

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