Elemental abundances of extrinsic carbon stars provide insight into the poorly understood origin and evolution of elements in the early Galaxy. In this work, we present the results of a detailed spectroscopic analysis of four potential carbon star candidates from the Hamburg/ESO Survey (HES) HE~04571805, HE~09200506, HE~12410337, and HE~13272116. This analysis is based on the high-resolution spectra obtained with Mercator/HERMES (R86,000) and SUBARU/HDS (R50,000). Although the abundances of a few elements, such as, Fe, C, and O are available from medium-resolution spectra, we present the first ever detailed high-resolution spectroscopic analysis for these objects. The object HE~04571805 and HE~12410337 are found to be CEMP-s stars, HE~09200506 a CH star, and HE~13272116 a CEMP-r/s star. The object HE~04571805 is a confirmed binary, whereas the binary status of the other objects is unknown. The locations of program stars on the absolute carbon abundance A© vs [Fe/H] diagram point at their binary nature. We have examined various elemental abundance ratios of the program stars and confirmed the low-mass nature of their former AGB companions. We have shown that the i-process models could successfully reproduce the observed abundance pattern in HE~13272116. The parametric model based analysis performed for HE~04571805, HE~09200506, and HE~12410337 based on the FRUITY models confirmed that the surface chemical composition of these three objects are influenced by pollution from low-mass AGB companions.

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