In this paper, we investigate the relationship between matched pairs of Lie algebras and Rota-Baxter Lie algebras. First, we show that every Rota-Baxter Lie algebra of weight gives rise to a matched pair of Lie algebras , and we prove that the bicrossed product Lie algebra decomposes as . Moreover, we establish a Rota-Baxter Lie algebra structure on which is isomorphic to as a Rota-Baxter Lie algebra, and we endow with a Rota-Baxter Lie algebra structure. Then we study the connection between quadratic Rota-Baxter Lie algebras and Manin triples. We prove that every quadratic Rota-Baxter Lie algebra of weight gives rise to a Manin triple, and we obtain a decomposition theorem for this Manin triple. Finally, we show that every Rota-Baxter group induces a matched pair of groups and investigate the internal structure of the induced matched pair of groups.

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