Impact Induced Atmosphere-Mantle Exchange Sets the Volatile Elemental Ratios on Primitive Earths

Conventional planet formation theory suggests that chondritic materials have delivered crucial atmospheric and hydrospheric elements such as carbon ©, nitrogen (N), and hydrogen (H) onto primitive Earth. However, recent measurements highlight the significant elemental ratio discrepancies between terrestrial parent bodies and the supposed planet building blocks. Here we present a volatile evolution model during the assembly of Earth and Earth-like planets. Our model includes impact losses, atmosphere-mantle exchange, and time dependent effects of accretion and outgassing calculated from dynamical modeling outcomes. Exploring a wide range of planetesimal properties (i.e., size and composition) as well as impact history informed by N-body accretion simulations, we find that while the degree of CNH fractionation has inherent stochasticity, the evolution of C/N and C/H ratios can be traced back to certain properties of the protoplanet and projectiles. Interestingly, the majority of our Earth-like planets acquire superchondritic final C/N ratios, implying that the volatile elemental ratios on terrestrial planets are driven by the complex interplay between delivery, atmospheric ablation, and mantle degassing.