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We identify laser-accessible transitions in group 16-like highly charged ions as candidates for high-accuracy optical clocks, including S-, Se-, and Te-like systems. For this class of ions, the ground fine structure manifold exhibits irregular (nonmonotonic in ) energy ordering for large enough ionization degree. We consider the (ground to first-excited state) electric quadrupole transition, performing relativistic many-body calculations of several atomic properties important for optical clock development. All ions discussed are suitable for production in small-scale ion sources and lend themselves to sympathetic cooling and quantum-logic readout with singly charged ions.

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