We apply the method of orbit harmonics to the set of break divisors and orientable divisors on graphs to obtain the central and external zonotopal algebras respectively. We then relate a construction of Efimov in the context of cohomological Hall algebras to the central zonotopal algebra of a graph constructed from a symmetric quiver with enough loops and a dimension vector . This provides a concrete combinatorial perspective on the former work, allowing us to identify the quantum Donaldson-Thomas invariants as the Hilbert series of the space of -invariants of the Postnikov-Shapiro slim subgraph space attached to . The connection with orbit harmonics in turn allows us to give a manifestly nonnegative combinatorial interpretation to numerical Donaldson-Thomas invariants as the number of -orbits under the permutation action on the set of break divisors on . We conclude with several representation-theoretic consequences, whose combinatorial ramifications may be of independent interest.

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