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In this paper, we are concerned with the coupled nonlinear Schrödinger system \begin{align*} \begin{cases} -\varepsilon^{2}Δu+a(x)u=μ_{1}u^{3}+βv^{2}u \ \ \ \ \mbox{in}\ ^{N},\ -\varepsilon^{2}Δv+b(x)v=μ_{2}v^{3}+βu^{2}v \ \ \ \ \ \mbox{in}\ ^{N}, \end{cases} \end{align*} where , , and are nonnegative continuous potentials, and is a small parameter. We show the existence of positive ground state solutions for the system above and also establish the concentration behaviour as , when and achieve 0 with a homogeneous behaviour or vanish in some nonempty open set with smooth boundary.

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