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In this work, we study the semiclassical limit of cubic Nonlinear Schrödinger equations for mixed states. We justify the limit to a singular Vlasov equation (in which the force field is proportional to the gradient of the density), for data with finite Sobolev regularity whose velocity profiles satisfy a quantum Penrose stability condition. This latter condition is always satisfied for small data (with a smallness condition independent of the semiclassical parameter) both in the focusing and the defocusing case, and for small perturbations of a large class of physically relevant examples in the defocusing case, such as local Maxwellian-like profiles.

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