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We construct a full exceptional collection consisting of vector bundles in the derived category of coherent sheaves on the so-called Cayley Grassmannian, the subvariety of the Grassmannian parameterizing 3-subspaces that are annihilated by a general 4-form. The main step in the proof of fullness is a construction of two self-dual vector bundles which is obtained from two operations with quadric bundles that might be interesting in themselves.

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