In this paper, we investigate the following fractional Sobolev critical nonlinear Schrödinger (NLS) coupled systems: \begin{equation*} \left{\begin{array}{lll} (-Δ)^{s} u=μ_{1} u+|u|^{2^{}{s}-2}u+η{1}|u|^{p-2}u+γα|u|^{α-2}u|v|^β ~ ~ ^{N},\ (-Δ)^{s} v=μ_{2} v+|v|^{2^{}{s}-2}v+η{2}|v|^{q-2}v+γβ|u|^α|v|^{β-2}v ~~~ ^{N},\ |u|^{2}{L^{2}}=m{1}^{2} ~~ |v|^{2}{L^{2}}=m{2}^{2}, \end{array}\right. \end{equation*} where is the fractional Laplacian, , , are unknown constants, which will appear as Lagrange multipliers, is the fractional Sobolev critical index, , , . Firstly, if , we obtain the existence of positive normalized solution when is big enough. Secondly, if , we show that nonexistence of positive normalized solution. The main ideas and methods of this paper are scaling transformation, classification discussion and concentration-compactness principle.

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