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Up to dimension five, we can prove that given any closed Riemannian manifold with nonnegative scalar curvature, of which the universal covering has vanishing homology group for all , either it is flat or it has Gauss-Bonnet quantity (defined by (1.3)) no greater than . In the second case, the equality for Gauss-Bonnet quantity yields that the universal covering splits as the Riemannian product of a -sphere with non-negative sectional curvature and the Euclidean space. We also establish a dominated version of this result and its application to homotopical -systole estimate unifies the results from [BBN10] and [Zhu20].

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