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The aim of this paper is to deal with BiHom-alternative algebras which are a generalization of alternative and Hom-alternative algebras, their structure is defined with two commuting multiplicative linear maps. We study cohomology and one-parameter formal deformation theory of left BiHom-alternative algebras. Moreover, we study central and -extensions of BiHom-alternative algebras and their relationship with cohomology. Finally, we investigate generalized derivations and give some relevant results.

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