This study addresses optimal impulsive trajectory design within the Circular Restricted Three-Body Problem (CR3BP), presenting a global optimization-based approach to identify minimum transfers between periodic orbits, including heteroclinic connections. By combining a Monotonic Basin Hopping (MBH) algorithm with a sequential quadratic solver in a parallel optimization framework, a wide range of minimum transfers are efficiently found. To validate this approach, known connections from the literature are reproduced. Consequently, three-dimensional periodic orbits are explored and a systematic search for minimum propellant trajectories is conducted within a selected interval of Jacobi constants and a maximum time of flight. Analysis of the results reveals the presence of very low solutions and showcases the algorithm’s effectiveness across various mission scenarios.

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