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The axion-gluon coupling can be constrained directly through hard exclusive processes at the LHC. Specifically, we study the associated production of a long-lived axion with a meson in ultra-peripheral collisions and in collisions. With the axion escaped from the detector, the final state is characterized by a mono-hadron signature. The main background in our analysis originates from the process, where the photons from the decay are undetected due to limited detector performance. Our analysis yields an exclusion limit of the axion-gluon coupling that is comparable to the limit obtained from the mono-jet process at the LHC.

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