We address some open problems concerning Banach spaces of real-valued Lipschitz functions. Specifically, we prove that the diameter two properties differ from their weak-star counterparts in these spaces. In particular, we establish the existence of dual Banach spaces lacking the symmetric strong diameter two property but possessing its weak-star counterpart. We show that there exists an octahedral Lipschitz-free space whose bidual is not octahedral. Furthermore, we prove that the Banach space of real-valued Lipschitz functions from any infinite subset of possesses the symmetric strong diameter two property. These results are achieved by introducing new sufficient conditions, providing new examples and clarifying the status of known ones.

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