We investigate the ground-state phase diagram of a binary mixture of Bose-Einstein condensates (BECs) with competing interspecies - and -wave interactions. Exploiting a pseudopotential model for the partial wave, we derive an extended Gross-Pitaevskii (GP) equation for the BEC mixture that incorporates both - and -wave interactions. Based on it, we study the miscible-immiscible transition of a binary BEC mixture in the presence of interspecies -wave interaction, by combining numerical solution of the GP equation and Gaussian variational analysis. Our study uncovers a dual effect – either enhance or reduce miscibility – of positive interspecies -wave interaction, which can be precisely controlled by adjusting relevant experimental parameters. By complete characterizing the miscibility phase diagram, we establish a promising avenue towards experimental control of the miscibility of binary BEC mixtures via high partial-wave interactions.

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