The spin-orbit splitting between neutron 1 orbitals at Si has been deduced using the single-neutron-adding (,) reaction in inverse kinematics with a beam of Si, a long-lived radioisotope. Reaction products were analyzed by the newly implemented SOLARIS spectrometer at the reaccelerated-beam facility at the National Superconducting Cyclotron Laboratory. The measurements show reasonable agreement with shell-model calculations that incorporate modern cross-shell interactions, but they contradict the prediction of proton density depletion based on relativistic mean-field theory. The evolution of the neutron 1-shell orbitals is systematically studied using the present and existing data in the isotonic chains of , 19, and 21. In each case, a smooth decrease in the separation of the - orbitals is seen as the respective -orbitals approach zero binding, suggesting that the finite nuclear potential strongly influences the evolution of nuclear structure in this region.

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