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Polyethylene naphthalate (PEN) foils have been demonstrated as a wavelength shifter suitable for operation in liquid argon. At the same time, wavelength shifting efficiency of technical grades of PEN, commercially available on the market, is lower than that of tetraphenyl butadiene (TPB). This paper reports on an R&D program focused on exploring the intrinsic limitations of PEN and optimizing it for the highest achievable wavelength shifting efficiency.

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