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Resonant positron annihilation on atomic electrons provides a powerful method to search for light new particles coupled to . Reliable estimates of production rates require a detailed characterization of electron momentum distributions. We describe a general method that harnesses the target material Compton profile to properly include electron velocity effects in resonant annihilation cross-sections. We additionally find that high atoms can efficiently act as particle physics accelerators, providing a density of relativistic electrons that allows to extend by several times the experimental mass reach.

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