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We characterise the positive cone of a real C*-algebra geometrically. Given an open cone in a real Banach space , with closure , we show that is the interior of the positive cone of a unital real C*-algebra if and only if it is a Finsler symmetric cone with an orientable extension, which is equivalent to the condition that is, in an equivalent norm, the hermitian part of a unital real C*-algebra with positive cone .

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