Using advanced dynamical mean-field theory on a realistic level we study the normal-state correlated electronic structure of the high-pressure superconductor LaNiO and compare the features of the conventional bilayer (2222) Ruddelsden-Popper crystal structure with those of a newly-identified monolayer-trilayer (1313) alternation. Both structural cases display Ni- flat-band character at low-energy, which drives an electronic instability with a wave vector at ambient pressure, in line with recent experimental findings. The 1313 electronic structure exhibits significant layer selectivity, rendering especially the monolayer part to be Mott-critical. At high pressure, this layer selectivity weakens and the 1313 fermiology displays arcs reminiscent to those of high- cuprates. In contrast to dominant inter-site self-energy effects in the latter systems, here the Fermi arcs are the result of the multiorbital and multilayer interplay within a correlated flat-band scenario.

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