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Taking the tri-bimaximal flavor mixing pattern as a particular basis, we propose a new way to expand the unitary Pontecorvo-Maki-Nakagawa-Sakata (PMNS) lepton flavor mixing matrix in powers of the magnitude of its smallest element . Such a Wolfenstein-like parametrization of allows us to easily describe the salient features and fine structures of flavor mixing and CP violation, both in vacuum and in matter.

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