Given any compact homogeneous space with simple, we consider the new space , where denotes diagonal embedding, and study the existence, classification and stability of -invariant Einstein metrics on , as a first step into the largely unexplored case of homogeneous spaces of compact non-simple Lie groups. We find unstable Einstein metrics on for most spaces such that their standard metric is Einstein (e.g., isotropy irreducible) and the Killing form of is a multiple of the Killing form of (e.g., simple), a class which contains families and individual examples. A complete classification is obtained in the case when is an irreducible symmetric space with simple. We also study the behavior of the scalar curvature function on the space of all normal metrics on (none of which is Einstein), obtaining that the standard metric is a global minimum.

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