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We study the interplay between geometrically-Bott-Chern-formal metrics and SKT metrics. We prove that a -dimensional nilmanifold endowed with a invariant complex structure admits an SKT metric if and only if it is geometrically-Bott-Chern-formal. We also provide some partial results in higher dimensions for nilmanifolds endowed with a class of suitable complex structures. Furthermore, we prove that any Kähler solvmanifold is geometrically formal. Finally, we explicitly construct lattices for a complex solvable Lie group in the list of Nakamura [23] on which we provide a non vanishing quadruple -Massey product.

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