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We derive solutions of the Schrödinger equation for the isotropic van der Waals interaction in a symmetric harmonic trap, with the recent approach [arXiv:2207.09377 (2022)] to handle the multi-scale long-range potential. Asymptotic behaviors of these solutions are then obtained for and . We further deduce the energy spectrum of the two-body relative motion and relate the spectrum to scattering lengths for wave and wave. These results can be used to research trapped atom-atom collisions and energy spectra.

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