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Let . Let be a noncommutative symmetric diffusion semigroup on a semifinite von Neumann algebra , and let be its associated subordinated Poisson semigroup. The celebrated noncommutative Littlewood-Paley-Stein inequality asserts that for any , \begin{equation*} α_p^{-1}|x|{p}\le |x|{p,P}\le β_p |x|_{p}, \end{equation*} where is the -norm of square functions associated with , and are the best constants only depending on . We show that as , and is the optimal possible order of as well. We also obtain some lower and upper bounds of and in the other cases.

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