In this paper, we develop the PBW theory for the bosonic extension of a quantum group of \emph{any} finite type. When belongs to the class of \emph{simply-laced type}, the algebra arises from the quantum Grothendieck ring of the Hernandez-Leclerc category over quantum affine algebras of untwisted affine types. We introduce and investigate a symmetric bilinear form on which is invariant under the braid group actions on , and study the adjoint operators and with respect to . It turns out that the adjoint operators and are analogues of the -derivations and on the negative half of . Following this, we introduce a new family of subalgebras denoted as in . These subalgebras are defined for any elements in the positive submonoid of the (generalized) braid group of . We prove that exhibits PBW root vectors and PBW bases defined by for any sequence of . The PBW root vectors satisfy a Levendorskii-Soibelman formula and the PBW bases are orthogonal with respect to . The algebras can be understood as a natural extension of quantum unipotent coordinate rings.

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