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In this paper, we investigate the thermodynamic properties of charged AdS Gauss-Bonnet black holes and the associations with the Lyapunov exponent. The chaotic features of the black holes and the isobaric heat capacity characterized by Lyapunov exponent are studied to reveal the stability of black hole phases. With the consideration of both timelike and null geodesic, we find the relationship between Lyapunov exponent and Hawking temperature can fully embody the feature of the Small/Large phase transition and the triple point even further. Then we briefly reveal the properties of Lyapunov exponent as an order parameter and explore the black hole shadow with it.

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