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We obtain asymptotics of polynomials satisfying the orthogonality relations where the complex parameter is in the so-called two-cut region. As an application, we deduce asymptotic formulas for certain families of solutions of Painlevé-IV which are indexed by a non-negative integer and can be written in terms of parabolic cylinder functions. The proofs are based on the characterization of orthogonal polynomials in terms of a Riemann-Hilbert problem and the Deift-Zhou non-linear steepest descent method.

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