The cluster structure of the neutron-rich isotope Be has been probed via the reaction at 150 MeV/nucleon in inverse kinematics and in quasifree conditions. The populated states of He residues were investigated through missing mass spectroscopy. The triple differential cross-section for the ground-state transition was extracted for quasifree angle pairs (, ) and compared to distorted-wave impulse approximation reaction calculations performed in a microscopic framework using successively the Tohsaki-Horiuchi-Schuck-Röpke product wave-function and the wave-function deduced from Antisymmetrized Molecular Dynamics calculations. The remarkable agreement between calculated and measured cross-sections in both shape and magnitude validates the molecular structure description of the Be ground-state, configured as an - core with two valence neutrons occupying -type molecular orbitals.

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