In this work, the spectra of the prospective exotic hidden-charm and hidden-bottom baryonium, viz. the baryon-antibaryon states, with and are investigated in the framework of QCD sum rules. The non-perturbative contributions up to dimension 12 are taken into account. Numerical results indicate that there might exist 3 possible hidden-charm baryonium states with masses , , and GeV, and 5 possible hidden-charm baryonium states with masses , , , , and GeV, respectively. The corresponding hidden-bottom partners are found lying in the range of GeV and GeV, respectively. The possible baryonium decay modes are analyzed, which are hopefully measurable in LHC experiments.

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