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We study 4-dimensional Poincaré-Einstein manifolds whose conformal class contains a Kähler metric. Such Einstein metrics are non-Kähler and admit a Killing field extending to the conformal infinity, and the Einstein equation reduces to a Toda-type equation. When the Killing field integrates to an -action, we formulate a Dirichlet boundary value problem and establish existence and uniqueness theory. This construction provides a non-perturbative realization of infinite-dimensional families of new Poincaré-Einstein metrics whose conformal infinities are of non-positive Yamabe type.

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